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阴离子高分子脱墨剂P(AA-BE)的制备及其脱墨性能研究

Preparation of Anionic Poly(acrylic acid-polyoxyethylene acrylate) and Its Performance as Deinking Agent

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【作者】 费贵强沈一丁王海花

【Author】 FEI Gui-qiang,SHEN Yi-ding,WANG Hai-hua(Institute of light chemical industry materials and design,Shaanxi University of Science & Technology,Xian 710021,China)

【机构】 陕西科技大学轻化工材料与设计研究所陕西科技大学轻化工材料与设计研究所 陕西西安710021陕西西安710021

【摘要】 采用水溶液聚合法,以丙烯酸(AA)、丙烯酸聚氧乙烯酯(BE)合成了一系列阴离子型P(AA-BE)高分子脱墨剂。考察了其最佳合成工艺,并研究了该产品与非离子型表面活性剂复配应用效果。结果表明,当n(AA)∶n(BE)=4∶1,聚合温度为80℃,w(APS)=2.5%时,可达最佳脱墨效果;P(AA-BE)与AEO-9复配可取得较佳效果,当m[P(AA-BE)]∶m(AEO-9)=2∶1,用量0.2%(其他助剂一定)时,废旧报纸纸张白度可达65.3%,残余油墨量仅为198.3 mg/kg。

【Abstract】 A series of anionic poly(acrylic acid-polyoxyethylene acrylate) [P(AA-BE)] deinking agents were synthesized by aqueous solution polymerization of acrylic acid(AA) and polyoxyethylene acrylate(BE).The synthesis process was optimized.The combined performance of P(AA-BE) deinking agent with nonionic surfactants was investigated.It was found that the best deinking effect can be obtained when the preparation conditions of the P(AA-BE) was as follows: n(AA) ∶n(BE)=4 ∶1;w(APS)=2.5%;reaction temperature=80 ℃.The P(AA-BE) shows better performance when used together with AEO-9.When m[P(AA-BE)] ∶m(AEO-9)=2 ∶1 and P(AA-BE) is 0.2%;the whiteness can be reached as 61.3% and the residual ink concentration is only 198.3 mg/kg.

【基金】 国家自然科学基金项目(50473049;50673055)
  • 【文献出处】 造纸化学品 ,Paper Chemicals , 编辑部邮箱 ,2008年02期
  • 【分类号】TS74
  • 【被引频次】16
  • 【下载频次】129
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