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C/SiC复合陶瓷与铌合金的活性钎焊

Study on Active Reactive Brazing of C/SiC Ceramic to Nb Alloy

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【作者】 陆艳杰张小勇楚建新刘鑫方针正

【Author】 Lu Yanjie,Zhang Xiaoyong,Chu Jianxin,Liu Xin,Fang Zhenzheng (Metallurgy and Special Materials Research Department,General Research Institute for Non-Ferrous Metals,Beijing 100088,China)

【机构】 北京有色金属研究总院粉末冶金及特种材料研究所

【摘要】 用Ag-Cu-Ti活性钎料对C/SiC复合陶瓷与Nb合金进行了真空钎焊。结果表明,适合该陶瓷钎焊的Ag-Cu-Ti钎料的Ti含量以2.5%~3.0%(质量分数)为宜;但Ag-Cu-Ti2.5钎料直接钎焊陶瓷与金属,焊缝及陶瓷一侧有裂纹和孔洞等缺陷;钎料中引入Mo颗粒后有效缓解了残余应力,实现了陶瓷与金属的气密连接,界面反应产物主要是TiC,TiSi,Cu4Ti,Cu3Ti。

【Abstract】 The C/SiC ceramic was brazed to Nb alloy in vacuum using Ag-Cu-Ti brazing alloys. The results showed that the 2.5%~3.0%Ti (mass fraction) in brazing alloy was advisable for brazing C/SiC ceramic. However C/SiC could not be bonded reliably to Nb alloy straight using Ag-Cu-Ti2.5 because of high residual stress. In practice,the AgCuTi2.5-Mo material could joint them and the joint was highly gastight,depending on the 40%Mo (volume fraction) grains which could distinctly release the thermal stress,and the main reaction products were TiC,TiSi,Cu4Ti,Cu3Ti.

【关键词】 C/SiC活性钎焊残余应力润湿性
【Key words】 C/SiC ceramicactive brazingresidual stresswettability
【基金】 国家“863”计划项目(2006AA03A220)资助
  • 【文献出处】 稀有金属 ,Chinese Journal of Rare Metals , 编辑部邮箱 ,2008年05期
  • 【分类号】TG454
  • 【被引频次】14
  • 【下载频次】273
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