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两种改性磷矿粉的制备与表征

Preparation and testing of two kinds of modified phosphorite powder

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【作者】 冯兆滨刘秀梅刘光荣邹绍文张树清张建峰王玉军张夫道

【Author】 FENG Zhao-bin1,LIU Xiu-mei1,LIU Guang-rong1,ZOU Shao-wen1,ZHANG Shu-qing2,ZHANG Jian-feng2,WANG Yu-jun2,ZHANG Fu-dao2(1 Soil and Fertilizer Institute,Jiangxi Academy of Agricultural Sciences,Nanchang 330200,China;2 Institute of Agricultural Resources and Regional Planning,Chinese Academy of Agricultural Science,Beijing 100081,China)

【机构】 江西省农业科学院土壤肥料研究所中国农业科学院农业资源与农业区划研究所

【摘要】 选用天然磷矿粉为原材料,通过硫酸酸化、有机无机活化剂活化分别制得酸化磷矿粉和活化磷矿粉。采用扫描电镜观察、X-射线衍射分析、激光粒度测试,证明了90%的酸化磷矿粉粒径为4.227μm,90%的活化磷矿粉粒径达到220 nm。活化磷矿粉结晶度降低,比表面积增大,有利于磷素在土壤中的释放与吸附。此种制备方法开辟了磷肥生产新工艺。

【Abstract】 The natural phosphorite powder was selected to prepare activated phosphorite powder and acidic phosphorite powder by a method of H2SO4 acidification and organic-inorganic agent activation,and several testing instruments including the scan electron-microscope(SEM),the X-ray diffraction(XRD) and the laser granularity,were used to determine the types of phosphorite powder.It was verified that the particle size of more than 90% of the acidic phosphorite powder was less than 4.227 μm,and more than 90% of activated phosphorite powder was less than 220 nm.Additionally,the crystallization of activated phosphorite powder declined,and the surface area increased.

【关键词】 活化磷矿粉制备表征
【Key words】 activationphosphorite powderpreparationtesting
【基金】 国家863计划课题“纳米肥料关键技术研究”(2001AA218041)资助;国家“十一五”支撑计划“南方丘陵岗地红黄壤区沃土技术模式研究与示范”项目(2006BAD25B08)资助
  • 【文献出处】 植物营养与肥料学报 ,Plant Nutrition and Fertilizer Science , 编辑部邮箱 ,2008年04期
  • 【分类号】TD98
  • 【被引频次】15
  • 【下载频次】307
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