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几种铵盐对土壤吸附Cd2+和Zn2+的影响

Effects of NH4+ salts on sorption of Cd2+ and Zn2+ in soils

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【作者】 张桃红徐国明陈苗苗张桂银袁建华

【Author】 ZHANG Tao-hong~(1,2) XU Guo-ming~1 CHEN Miao-miao~1 ZHANG Gui-yin~(1*) YUAN Jian-hua~3 1 College of Resource and Environment Science,Agricultural University of Hebei,Baoding 071001,China; 2 Bazhou Environment Protection Monitoring Station,Bazhou,Hebei 065700,China; 3 Bazhou Water Corporation,Bazhou,Hebei 065700,China

【机构】 河北农业大学资源与环境科学学院霸州市自来水公司 河北保定 071001 霸州市环境保护局监测站河北霸州 065700河北保定 071001

【摘要】 采用平衡吸附法,研究了不同铵盐对潮褐土、红壤吸附Cd2+、Zn2+的影响。结果表明,土壤对Cd2+、Zn2+的吸附量随平衡溶液中Cd2+、Zn2+浓度的增加而增加;潮褐土和红壤对Cd2+、Zn2+的最大吸附量为:Zn2+>Cd2+,且潮褐土>红壤;随NH4HCO3浓度的增加,两种土壤对Cd2+、Zn2+的吸附率显著提高,NH4Cl、NH4NO3和(NH42SO4抑制红壤对Cd2+、Zn2+的吸附及潮褐土对Cd2+的吸附,对潮褐土Zn2+的吸附率影响不显著;铵盐浓度相同时,红壤对Cd2+吸附率为NH4HCO3>NH4Cl>NH4NO3≈(NH42SO4,红壤对Zn2+吸附率为NH4HCO3>NH4Cl>NH4NO3>(NH42SO4

【Abstract】 The effects of different NH4+ salts on Cd2+ and Zn2+ sorption in meadow cinnamon soils(MCS)and red soils (RS)were evaluated by batch method.The results showed that Cd2+ and Zn2+ amounts adsorbed by soils increased with the initial concentrations of added Cd2+ and Zn2+.The maximum amount of Cd2+ and Zn2+ sorption on MCS and RS were:Zn2+>Cd2+.The maximum amount of heavy metal ions adsorbed on soils was greater in meadow cinnamon soil than in red soil.The sorption percentage of Cd2+ and Zn2+ by soils decreased in the presence of NH4HCO3.NH4+ salts, such as NH4Cl,NH4NO3,and (NH42SO4 restrained Cd2+ and Zn2+ sorption in RS and Cd2+ sorption in MCS.There was no significant effect of NH4Cl,NH4NO3,and (NH42SO4 on Zn2+ sorption in MCS.At the same concentration of NH4+ salts,Cd2+ sorption percentage in RS was decreased in the following order:NH4HCO3>NH4Cl>NH4NO3≈(NH42SO4,and Zn2+ sorption percentage in RS in the following order:NH4HCO3>NH4Cl>NH4NO3>(NH42SO4.

【关键词】 土壤铵盐吸附
【Key words】 soilNH4+ saltCdZnsorption
【基金】 河北省自然科学基金项目(D2004000390)资助。
  • 【文献出处】 植物营养与肥料学报 ,Plant Nutrition and Fertilizer Science , 编辑部邮箱 ,2008年03期
  • 【分类号】X131.3
  • 【被引频次】9
  • 【下载频次】178
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