【摘要】 制备了一个新型的三维超分子化合物:镉-二茂铁亚甲基苯并咪唑配合物[Cd(FB IM)2I2](FB IM=二茂铁亚甲基苯并咪唑),并通过X-射线衍射仪对其晶体结构进行了表征。循环伏安测试结果表明其氧化还原过程是受扩散控制的,计时电流法和计时电量法测得其扩散系数分别为1.02×10-5和1.36×10-5cm2/s。更多还原

【Abstract】 A novel 3-D superamolecular network [Cd(FBIM)2I2] 1(FBIM = ferrocenyl methyl benzimidazole) has been synthesized and structurally characterized by x-ray single crystal diffraction.The cyclic voltammetry(CV) studies show that the redox processes of 1 is controlled by the diffusion.The diffusion coefficients(D) are obtained from chronocoulometry(CC) and chronoamperometry(CA) methods.The D values are 1.02×10-5 and 1.36 ×10-5 cm2/s,respectively.更多还原