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CuH分解制备铜基催化剂及其催化CO氧化反应的活性研究(英文)

Preparation of Cu-based catalysts via the decomposition of CuH precursor and their catalytic activities in CO oxidation

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【作者】 毕兴震姜志全黄伟新

【Author】 BI Xing-zhen,JIANG Zhi-quan,HUANG Wei-xin(Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemical Physics,University of Science and Technology of China,Hefei 230026,China)

【机构】 中国科学技术大学微尺度物质科学国家实验室和化学物理系中国科学技术大学微尺度物质科学国家实验室和化学物理系 安徽合肥230026安徽合肥230026

【摘要】 宏量制备CuH纳米粒子,并通过CuH纳米粒子在不同气氛下的热分解制备了具有不同组成和结构的铜基催化剂.CuH纳米粒子在N2中分解制备的催化剂表现出最好的CO催化氧化活性,而CuH纳米粒子在O2中分解制备的催化剂表现出最差的CO催化氧化活性.基于上述结果讨论了铜基催化剂在CO氧化反研究快报

【Abstract】 CuH nanoparticles were synthesized and employed as the precursor for the preparation of unsupported Cu-based catalysts.Thermal decomposition of CuH under different atmospheric conditions led to the formation of Cu-based catalysts with different compositions and structures.The catalyst prepared by the CuH decomposition under the N2 atmosphere exhibits the best catalytic performance in CO oxidation whereas the catalyst prepared by the CuH decomposition under the O2 atmosphere exhibits the worst catalytic performance.The structure-activity relation of various Cu-based catalysts was also discussed.

【基金】 National Natural Science Foundation of China(20503027);“100 Talents Program”of Chinese Academy of Sciences.
  • 【文献出处】 中国科学技术大学学报 ,Journal of University of Science and Technology of China , 编辑部邮箱 ,2008年06期
  • 【分类号】O643.36
  • 【下载频次】101
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