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松香酯的合成及应用

Synthesis and Application of Linear Rosin Ester Sizer

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【作者】 刘玉新胡惠仁牛梅红孙兵

【Author】 LIU Yu-xin1,HU Hui-ren1,NIU Mei-hong2,SUN Bing1 (1.Tianjin University Science & Technolony, Tianjin Key Laboratory of Pulp and Paper, Tianjin, 300457 China;2.Dalian Polytechnic University, Dalian, 116034 China)

【机构】 天津科技大学天津市制浆造纸重点实验室大连工业大学天津科技大学天津市制浆造纸重点实验室 天津300457天津300457辽宁大连116034

【摘要】 本文以改性松香和二甘醇为原料,合成线性松香酯。对松香酯的合成工艺进行了研究,并从原料配比、升温方式、催化剂用量等几个方面讨论了它们对线性松香酯合成的影响。同时,本文也研究了施胶pH值、施胶剂用量等对线性松香酯施胶效率的影响。结果表明,采用阳离子淀粉及阳离子聚丙烯酰胺作为复合型助留剂时,对漂白亚硫酸氢镁法苇浆和漂白硫酸盐木浆的混合浆料进行施胶,其最佳施胶pH值为7.0,在此条件下,施胶度可达90s以上。

【Abstract】 In this paper, linear rosin ester sizer was synthesized from modified rosin and diethylene glycol. Some influence factors on synthesis were discussed, such as raw material ratio, heating mode, dosage of catalyst. The effect of the pH value and the dosage of size on sizing effect were studied as well. The results show that with the dual retention system(cationic starch and CPAM), the optimized sizing pH is 7.0 and the sizing degree could reach 90s or higher, when the mixed furnish(composed of bleached magnesium bisulfite reed pulp and bleached kraft pulp) is sized by the rosin ester sizer.

【关键词】 松香酯合成中性施胶
【Key words】 rosin estersynthesisneutral sizing
  • 【文献出处】 纸和造纸 ,Paper and Paper Making , 编辑部邮箱 ,2008年01期
  • 【分类号】TS727
  • 【被引频次】10
  • 【下载频次】357
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