节点文献

在离子液体中钛硅分子筛催化氧化环己烷(英文)

Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 WANG Jianying1 ,2,ZHAO Hua2,ZHANG Xiangjing2,LIU Runjing2 and HU Yongqi1,2 1College of Chemical Engineering,Beijing Unversity of Chemical Technology,Beijing 100029,China 2College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,China

【机构】 College of Chemical Engineering Beijing Unversity of Chemical Technology； College of Chemical and Pharmac4eutical Engineering； Hebei University of Science and Technology； College of Chemical and Pharmaceutical Engineering； College of Chemical Engineering； Beijing Unversity of Chemical Technology； Beijing 100029； China； Shijiazhuang 050018；

【摘要】 An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1 (TS-1) in ambient-temperature ionic liquid [emim]BF4. Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent. The research results showed 13.2% conversion of cyclohexane, 97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90oC.更多还原

【Abstract】 An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1(TS-1)in ambient-temperature ionic liquid[emim]BF4.Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent.The research results showed 13.2%conversion of cyclohexane,97.6%cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90oC.更多还原

【关键词】 ionic liquid； cyclohexane； TS-1； tert-butyl-hydroperoxide；
【Key words】 ionic liquid； cyclohexane； TS-1； tert-butyl-hydroperoxide；

【基金】 the National Natural Science Foundation of China (20776037)

【文献出处】 Chinese Journal of Chemical Engineering ,中国化学工程学报(英文版) , 编辑部邮箱 ,2008年03期

【分类号】O643.32
【被引频次】12
【下载频次】228

知网节下载

节点文献中：

本文链接的文献网络图示:

本文的引文网络

节点文献