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Study on thermal expansion behavior of Dy2O3-Al2O3-SiO2 glass

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【作者】 刘玉柱耿志挺庄卫东何华强

【Author】 LIU Yuzhu1, GENG Zhiting 2, ZHUANG Weidong1, HE Huaqiang 1 (1. National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals, and Grirem Advanced Materials Co. Ltd., Beijing 100088, China; 2. Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China)

【机构】 National Engineering Research Center for Rare Earth Materials General Research Institute for Nonferrous Metals and Grirem Advanced Materials Co. Ltd.Department of Materials Science and Engineering Tsinghua UniversityNational Engineering Research Center for Rare Earth Materials General Research Institute for Nonferrous Metals and Grirem Advanced Materials Co. Ltd.Beijing 100088 ChinaBeijing 100084 ChinaBeijing 100088 ChinaBeijing 100088 China 2.

【摘要】 Employing Dy2O3, Al2O3, and SiO2 as starting materials, several series of Dy2O3-Al2O3-SiO2 sealing glass were prepared. The re- lationship between their coefficients of thermal expansion and the contents of Dy2O3, Al2O3, and SiO2 were studied respectively. Experimen- tal results showed that Dy2O3 and Al2O3 had a positive effect on the coefficient of thermal expansion of glass, whereas, SiO2 had a negative effect. The coefficient of thermal expansion of glass showed an apparent linear relation to the contents of these three raw materials, from which an estimation model was built, to calculate the coefficient of thermal expansion of sealing glass. Relative errors of the calculating re- sults to testing results were no more than 2%, which suggested that the estimation model was reasonable. This study provides a good theory reference for the practical utilizing of this sealing material, through which a proper glass composition for good sealing could be easily found.

【Abstract】 Employing Dy2O3, Al2O3, and SiO2 as starting materials, several series of Dy2O3-Al2O3-SiO2 sealing glass were prepared. The re- lationship between their coefficients of thermal expansion and the contents of Dy2O3, Al2O3, and SiO2 were studied respectively. Experimen- tal results showed that Dy2O3 and Al2O3 had a positive effect on the coefficient of thermal expansion of glass, whereas, SiO2 had a negative effect. The coefficient of thermal expansion of glass showed an apparent linear relation to the contents of these three raw materials, from which an estimation model was built, to calculate the coefficient of thermal expansion of sealing glass. Relative errors of the calculating re- sults to testing results were no more than 2%, which suggested that the estimation model was reasonable. This study provides a good theory reference for the practical utilizing of this sealing material, through which a proper glass composition for good sealing could be easily found.

【基金】 Project supported by the Ministry of Science and Technology of China (2006CB601104)
  • 【文献出处】 Journal of Rare Earths ,稀土学报(英文版) , 编辑部邮箱 ,2008年01期
  • 【分类号】TG139.8
  • 【被引频次】3
  • 【下载频次】66
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