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反应性二苯醚类抗菌整理剂的制备及应用

Preparation and application of reactive diphenyl ether antibacterial agent

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【作者】 殷志剑郭玉良沈华金雅朱泉石碧

【Author】 YIN Zhi-jian1,GUO Yu-liang1,2,SHEN Hua1,JIN Ya1,ZHU Quan1,SHI Bi2(1.Key Lab.Ministry Edu.Eco.Text.,Donghua Univ.,Shanghai 201620,China;2.Key Lab.Leather Chem. Eng.Ministry Edu.,Sichuan Univ.,Chengdu 610065,China)

【机构】 东华大学生态纺织教育部重点实验室四川大学皮革化学与工程教育部重点实验室 上海201620上海201620四川大学皮革化学与工程教育部重点实验室四川成都610065

【摘要】 以2,4,4-′三氯-2-′羟基二苯醚和异氰酸丙基三乙氧基硅烷为原料合成了一种反应性二苯醚类抗菌整理剂,通过红外光谱初步表征了其结构,探讨了其与织物的结合方式.抗菌性能测试结果表明:当抗菌整理剂乳液用量为20%(owf)时,整理织物经50次水洗后对大肠杆菌的抗菌率可达到94.46%,表明具有优良的抗菌效果和耐洗性能.物理机械性能测试结果表明:整理前后织物的白度、透气性、顶破强力等指标变化较小,表明该整理剂适宜于棉织物的耐久抗菌整理.

【Abstract】 2,4,4’-Trichloro-2’-hydroxydiphenyl ether and isocyanatoproppyltrimethoxysilane were used as raw materials for the synthesis of a reactive dimethyl ether antibacterial finishing agent,the product was characterized by IR spectrum and its binding mode on fabrics was investigated.The results of the antibacterial tests showed that excellent antibacterial results and washing resistance could be obtained on the fabrics finished with antibacrial emulsion at 20%(owf).The finished fabrics retained the antibacterial rate of 94.46% to Bacillus coli after 50 waterwashing cycles.The results of the physicomechanical tests showed that little index changes of fabric whiteness,breathability and bursting strength etc.happened after the finishing.It was proven that the product was suitable for durable antibacterial finishing of cotton fabrics.

【基金】 长江学者和创新团队发展计划资助(No.IRT0526)
  • 【文献出处】 印染助剂 ,Textile Auxiliaries , 编辑部邮箱 ,2008年01期
  • 【分类号】TS195.2
  • 【被引频次】6
  • 【下载频次】194
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