【摘要】 以二茂铁基丁酸(Fb)、4,4′-联吡啶(bpy)以及Zn(AC)2.2H2O为原料合成了一个新的混配合物Zn(Fb)2(bpy)2。X-射线单晶衍射分析表明,该化合物是一个四配体六配位单核配合物,并以氢键另连接两个二茂铁分子。更多还原

【Abstract】 A novel mixed-ligand complex [Zn(Fb)2(bpy)2]·2 HFb(Fb=4-ferrocenyl butyrate aniont,bpy=4,4′-Bipyrine) was obtained by the reaction of Zn(Ac)2·2H2O with sodium 4-ferrocenyl butyrate and 4,4′-Bipyrine in methanol solution.X-ray structural analysis reveals that it is a anisomerous uninuclear complex and in the compound both of 4-ferrocenyl butyric acid connects the complex by hydrogen bond N-H.更多还原