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改性剂和增塑剂对PVC微孔泡沫塑料形态影响

Effects of Modifying Agent and Plasticizer on Morphologies of PVC Microcellular Foam Plastics

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【作者】 王明义周南桥文生平湛丹

【Author】 Wang Mingyi Zhou Nanqiao Wen Shengping Zhan Dan (Key Laboratory of Polymer Processing Engineering,Ministry of Education, National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology,Guangzhou,Guangdong,510640)

【机构】 华南理工大学聚合物新型成型装备国家工程研究中心聚合物成型加工工程教育部重点实验室

【摘要】 以超临界CO2为发泡剂,用自制的动态模拟发泡装置研究了聚氯乙烯(PVC)配方中改性剂丙烯酸酯类高分子聚合物(ACR)含量和增塑剂邻苯二甲酸二辛酯(DOP)含量对PVC微孔塑料泡孔形态的影响。结果表明,在其他工艺条件和配方相同的情况下,ACR为4份时得到的PVC微孔泡沫塑料泡孔密度最大,泡孔粒径最小;DOP为2~6份时比较适合PVC微孔发泡,并且振动力场的引入有利于得到细小均匀的微孔结构。

【Abstract】 The effects of modifying agent ACR and plasticizer DOP on cell morphologies of polyvinyl chloride(PVC) microcellular foam plastics were studied with a self-designed dynamic simulation foaming setup and supercritical CO2 as foaming agent.The results show that as other processing conditions and components of the formulations are the same,PVC microcellular foam plastics with highest cell density and smallest cell size are obtained when content of ACR is 4 phr.It is suitable for microcellular foaming of PVC when content of DOP is from 2 phr to 6 phr,and introduction of vibration field is effective in obtaining fine and uniform microcellular structures.

  • 【文献出处】 现代塑料加工应用 ,Modern Plastics Processing and Applications , 编辑部邮箱 ,2008年05期
  • 【分类号】TQ328
  • 【被引频次】6
  • 【下载频次】254
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