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Structure and Properties of Mg-doped SrBi4Ti4O15 Bi-layered Compounds

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【作者】 郝华

【Author】 HAO Hua1,2, LIU Hanxing1,2,CAO Minghe2, OUYANG Shixi2 (1.School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China; 2.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China)

【机构】 School of Materials Science and Engineering, Wuhan University of TechnologyState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology

【摘要】 The structure and properties of Mg-doped SrBi4Ti4O15(SBT) were dicussed. Mg substitution into SBT had two possibilities states with the dopant amount variety. Mg cation substituted mostly into Sr2+ and the amount proportion was 68.11 %.Mg ion will substitute into Ti ion site in perovskite layer when the doping amount increases. Polarization increases sharply when x=0.1 and then decreases becauses of the domain pinning. The Curie temperature of Mg-doped SBT is about 300 ℃ and there is a broad diffuse phase transition near Tc with a flat peak near the Ta of SBT.

【Abstract】 The structure and properties of Mg-doped SrBi4Ti4O15(SBT) were dicussed. Mg substitution into SBT had two possibilities states with the dopant amount variety. Mg cation substituted mostly into Sr2+ and the amount proportion was 68.11 %.Mg ion will substitute into Ti ion site in perovskite layer when the doping amount increases. Polarization increases sharply when x=0.1 and then decreases becauses of the domain pinning. The Curie temperature of Mg-doped SBT is about 300 ℃ and there is a broad diffuse phase transition near Tc with a flat peak near the Ta of SBT.

【基金】 Funded by the Natural Science Foundation of China (No. 50472016, 50502027);the main project of the Ministry of Education (MOE) of China and the Chenguang Science Plan of Wuhan (No. 200750731268)
  • 【文献出处】 Journal of Wuhan University of Technology(Materials Science Edition) ,武汉理工大学学报(材料科学版)(英文版) , 编辑部邮箱 ,2008年05期
  • 【分类号】TG146.22
  • 【被引频次】1
  • 【下载频次】42
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