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全固态复合碳纤维氧化钨pH传感器的研制及应用

Preparation and Application of All-solid-state Combination CF/WO_x-pHSensor

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【作者】 杨百勤李靖杜宝中韩敏

【Author】 YANG Bai-qin1,LI Jing1,DU Bao-zhong2,HAN Min1,3(1.College of Chemistry and Chemical Engineering,Shaanxi University of Science & Technology,Xi’an 710021,China;2.Department of Applied Chemistry,Xi’an University of Technology,Xi’an 710048,China;3.Department of Chemistry,Xi’an University of Arts & Science,Xi’an 710065,China)

【机构】 陕西科技大学化学与化工学院西安理工大学应用化学系西安文理学院化学系

【摘要】 采用电化学修饰法制备了一种可直接测定固体、半固体及糊状物表面和内部pH值的传感器,并对该传感器的制备工艺、性能、测试条件和干扰物的影响进行了讨论。结果表明:该传感器内阻低,响应时间快(小于25 s),测量范围广(pH 2~12),准确度高,重复性好,响应斜率为60.01 mV/pH。该传感器除了能用于传统领域外,还可用于临床检测、食品加工、生物化工等领域。

【Abstract】 An all-solid-state combination sensor,which can be directly used to measure pH of the surface and inside of solid,semisolid and paste,was prepared by electrochemical modified method.The effects of preparation technology and property of the sensor,test condition and interference substance were discussed.The results indicated that the sensor had advantages of the lower inner resistance,rapid response time(t<25 s),wide measure range(pH 2-12),high measure precision,good reproducibility and a response slope of 60.01 mV/pH.Comparing with the general glass electrode,the combination sensor could be applied not only in some traditional fields,but also in clinical detection,food processing,biochemical engineering,and so on.

【关键词】 全固态pH传感器CF/WOxAg-AgCl电极
【Key words】 all-solid-statepH sensorCF/WOxAg-AgCl electrode
【基金】 陕西省咸阳市科技基金资助项目(XK06011-9)
  • 【文献出处】 分析测试学报 ,Journal of Instrumental Analysis , 编辑部邮箱 ,2008年11期
  • 【分类号】TP212.2
  • 【被引频次】6
  • 【下载频次】230
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