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河北平原深层地下水中氟含量与锶同位素组成的关系研究

Relation between F-Content and Strontium Isotopes Composition in Deep Groundwater of Hebei Plain

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【作者】 李小倩周爱国刘存富蔡鹤生叶萍甘义群武金博

【Author】 LI Xiao-qian,ZHOU Ai-guo,LIU Cun-fu,CAI He-sheng,YE Ping,GAN Yi-qun,WU Jin-bo(School of Environment,China University of Geosciences,Wuhan,430074,China)

【机构】 中国地质大学环境学院

【摘要】 本文对河北平原深层高氟地下水进行了研究,发现地下水中的氟含量与锶同位素组成(8δ7Sr)在水文地球化学性质上有3个相似点和一个明显的差异:①87Sr和F-有相同的矿物来源,例如黑云母、角闪石等,这可能是一个普遍的规律;②河北平原深层地下水的8δ7Sr值和其中的F-含量具有相似的分布规律,高值区都分布在子牙河附近及其以东的地区;③87Sr/86Sr比值(或8δ7Sr)与F-含量呈明显的正相关关系,都是水-岩作用"时间积累效应"的结果。二者的差异在于最大值的分布区不一致:8δ7Sr最大值分布区在子牙河一带,而F-含量最大值的分布区在吴桥-东光-沧州一带。本研究在一定程度上揭示了锶同位素对研究高氟地下水的形成机理、分布规律和生态效应的良好示踪作用。

【Abstract】 This paper studied deep groundwater of F-high content in Hebei Plain,and found that there are three similarities and a difference on relations between F-content and strontium isotopes composition,according to the study on Sr and F on geochemistry and hydrological geochemistry and δ87Sr /δ86Sr ratio of groundwater in Hebei Plain.(1)F-and 87Sr have the same sources,such as biotite and hornblende,which may be a universal phenomena;(2)δ87Sr value,and F-concentration have similar distribution that higher F-concentration(> 1.0 m/L) and higher δ87Sr value are both in the vicinity of Ziya River and the eastern area;(3)δ87Sr/δ86Sr radio is positively correlated with F-content in groundwater,reflecting the result of "time-accumulation" of water-rock inter-reaction.However,the maximum distribution area is not consistent.The δ87Sr maximum distributes around the Ziya River while the maximum distribution of F-is mainly in the region of Wuqiao-Dongguang-Cangzhou.The study revealed to a certain extent that strontium isotope plays a good tracer role to study the formation mechanism distribution and ecological effects of groundwater with high F-content.

【基金】 中国地质调查局地质调查项目(编号:200320150002);国家自然科学基金项目(编号:40372112,40572140,40602030)
  • 【文献出处】 水文 ,Journal of China Hydrology , 编辑部邮箱 ,2008年04期
  • 【分类号】P641.3
  • 【被引频次】6
  • 【下载频次】448
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