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成型温度对β晶型聚丙烯冲击强度的影响
Effect of Molding Temperature on Impact Strength of β-Modification Polypropylene
【摘要】 在两种不同等规聚丙烯中(iPP1,iPP2)加入0.1%的β-成核剂,通过测定其23℃、-20℃下的冲击强度,研究β晶聚丙烯的韧性随成型温度的变化规律。高β晶含量的iPP的冲击强度比α-iPP明显提高。随着成型温度上升,高β晶含量的iPP在23℃下的冲击强度降低。而成型温度在80~100℃区间时,-20℃下的冲击强度呈峰值。差示扫描量热仪分析结果表明,随着成型温度的升高,iPP-B样品中β晶的相对含量先上升后下降,在100℃附近出现峰值,与-20℃冲击强度呈正相关性。
【Abstract】 After adding 0.1% β-nucleating agent,isotactic polypropylene(iPP1,iPP2) were analysed in impact strength at 23℃ and -20℃ in order to study the relationship of ductility with molding temperature of β-PP.β-Modification iPP enhanced more than α-modification iPP in impact strength.With the molding temperature rising,impact strength of β-PP reduced at 23℃,while it had a peak value at-20℃ when molding temperature during 80~100℃.β-PP was analysed by DSC.It showed that the content of β-PP in iPP-B first fell then rose,appearing the peak value around 100℃.So the content of β-PP with impact strength at-20℃ presented the relevance.
【Key words】 polypropylene; β-modification; molding temperature; impact strength; DSC;
- 【文献出处】 塑料 ,Plastics , 编辑部邮箱 ,2008年02期
- 【分类号】TQ325.14
- 【被引频次】2
- 【下载频次】187