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原位聚合改性GF/SAN的界面模型及增韧机理研究

Study on Interfacial Model and Toughening Mechanism of GF/SAN Modified by In-situ Polymerization

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【作者】 曾武应继儒刘斌瞿金平

【Author】 Zeng wu1,Ying Jiru2,Liu Bin1,Qu jinping11.Key Laboratory of Polymer Processing Engineering of Ministry of Education,South China University of Technology,Guangzhou 510640,China 2.College of Chemical and Environmental Engineering,Hubei University of Technology,Wuhan 430068,China

【机构】 华南理工大学聚合物成型加工工程教育部重点实验室湖北工业大学化学与环境工程学院华南理工大学聚合物成型加工工程教育部重点实验室 广东广州510640湖北武汉430068广东广州510640

【摘要】 采用原位乳液聚合接枝法改善玻璃纤维(GF)与苯乙烯-丙烯腈共聚物(SAN)之间的界面黏结性能。对GF/SAN复合材料进行了冲击性能测试和微观结构分析,结果表明:原位聚合改性GF与SAN之间有良好的界面黏合力,可以有效地提高SAN的韧性。设计了一种新的界面模型,以解析原位聚合改性的GF与SAN界面的微观结构,并解释了GF/SAN复合材料的增韧机理。

【Abstract】 The in-situ emulsion polymerization technology was adopted to improve the interfacial adhesion between glass fiber(GF) and styrene-acrylonitrile copolymer(SAN).The impact property of GF/SAN composite was tested,and the microstructure of the composite was also analyzed.The results show that:the interfacial adhesion between GF modified by in-situ polymerization and SAN is excellent,modified GF could improve the toughness of SAN efficiently.An interfacial model was designed to explain the interfacial microstructure between modified GF and SAN.The toughening mechanism of GF/SAN composite was also explained.

【基金】 国家自然科学基金资助项目(10590351)
  • 【文献出处】 塑料科技 ,Plastics Science and Technology , 编辑部邮箱 ,2008年07期
  • 【分类号】TQ316.3
  • 【被引频次】4
  • 【下载频次】174
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