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X射线荧光光谱测定稀土铁氧体的方法研究

Determination of rare earth ferrite by X-ray fluorescence spectrometry

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【作者】 肖国拾陈博王威

【Author】 XIAO Guo-shi1,CHEN Bo2,WANG Wei31.Center of Testing Science & Experiment,Jilin University,Changchun 130026,China;2.College of Chemistry,Jilin University,Changchun 130026,China;3.No.2 Senior Middle School of Fushun City,Fushun 113006,Liaoning,China

【机构】 吉林大学测试科学实验中心吉林大学化学学院抚顺市第二高级中学

【摘要】 采用X射线荧光光谱分析方法,直接粉末压片测定磁铅石型稀土铁氧体中Fe、Ba、La等元素的浓度,实验结果表明:在最佳仪器工作条件下,测试结果的相对标准偏差均<1.71%(n=8);分析结果与理论值相比,镧测定相对误差<10.58%,其他元素测定误差均<2.23%。本方法具有制样方法简便、准确可靠和成本低等特点。

【Abstract】 The concentration of ferrum,barium and lanthanum elements in magnetoplumbite doped rare earth ferrites was directly determined by X-ray fluorescence spectrometry with the pressed powder samples.Under the suitable working condition for PW1404/10 type X-ray fluorescence spectrometer,the samples of hexagon ferrites doped rare earth were successively determined by the mentioned method.The relative standard deviation is less than 1.71%(n=8),the relative error is less than 10.58% for lanthanum,and 2.23% for ferrum and barium.This method is simple in making samples,and accurate and economic in characters.

【基金】 吉林省科技厅基金资助(20000512-2)
  • 【分类号】P575.5
  • 【被引频次】4
  • 【下载频次】97
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