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光度法快速测定铌铁中铌
Quick Determination of Niobium in Ferroniobium by Photometry
【摘要】 铌铁易溶于硝酸和氢氟酸的混合酸中,当用酸分解试样时,铌极易水解析出沉淀;但在氢氟酸存在下,又能成为可溶性络合物(H2NbF7),在分析铌铁中铌时,利用此特性,使铌保持于溶液中而用光度法进行铌的测定,实现光度法高速分析铌铁中的铌。
【Abstract】 Ferroniobium is apt to be dissolved in the mixture of nitric acid and hydrofluoric acid. When using nitric acid to dissolve ferroniobium sample, niobium is very apt to occur hydrolytic precipitation, but under the presence of hydrofluoric acid, it can become soluble complex(H2NbF7), so in the niobium analysis, usually to use this characteristic to keep niobium being solved in the solution so as to determine niobium with photometry, realizing rapid determination of niobium in ferroniobium with photometry.
【关键词】 铌铁;
铌;
二甲酚橙光度法;
氢氟酸;
可溶性络合物;
【Key words】 ferroniobium; niobium; xylenol orange spectrophotometry; hydrofluoric acid; soluble complex;
【Key words】 ferroniobium; niobium; xylenol orange spectrophotometry; hydrofluoric acid; soluble complex;
- 【文献出处】 山东冶金 ,Shandong Metallurgy , 编辑部邮箱 ,2008年06期
- 【分类号】TG115.33
- 【被引频次】9
- 【下载频次】134