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升温速率对生物质热解的影响

Effect of heating rate on biomass pyrolysis

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【作者】 任强强赵长遂

【Author】 REN Qiang-qiang, ZHAO Chang-sui(Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096, China)

【机构】 东南大学洁净煤发电及燃烧技术教育部重点实验室东南大学洁净煤发电及燃烧技术教育部重点实验室 江苏南京210096江苏南京210096

【Abstract】 The pyrolysis behavior of three typical agricultural residues including rice husk, rice straw and wheat straw, was studied at different heating rates(15℃/min, 40℃/min and 100℃/min) in a dynamic nitrogen flow of 80mL/min by TG analysis coupled with Fourier Transform Infrared Spectroscopy (FT-IR). The various gaseous products released during biomass pyrolysis were examined. The kinetic parameters under different heating rates were acquired by kinetics analysis. The correlation coefficients are above 0.99. The results show that as heating rate increases the TG curve shifts to low temperature zone and the peak of DTG curve goes to low temperature area accordingly, but the total weight loss and activation energy of pyrolysis fluctuate little. The releasing behavior of gaseous products during pyrolysis of the three samples is similar. CO, CO2, H2O, CH4 and organics are the main gaseous products during biomass pyrolysis. When the heating rate increases, the yield of gaseous products released increases, so does the releasing rate.

  • 【文献出处】 燃料化学学报 ,Journal of Fuel Chemistry and Technology , 编辑部邮箱 ,2008年02期
  • 【分类号】TK6
  • 【被引频次】53
  • 【下载频次】792
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