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活性炭间歇式吸附亚甲基蓝废水的研究

STUDY ON THE INTERMISSIVE ADSORPTION OF METHYLENE BLUE IN DYESTUFF WASTEWATER BY ACTIVATED CARBON

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【作者】 方雪坤胡宏吴顺志

【Author】 FANG Xue-kun1,HU Hong1,WU Shun-zhi2(1.College of Environmental and Resource Science,Zhejiang University,Hangzhou 310029,China;2.Hangzhou Environmental Protection Research Institute,CCRI,Hangzhou 311201,China)

【机构】 浙江大学环境与资源学院煤炭科学研究总院杭州环境保护研究所

【摘要】 以亚甲基蓝(MB)作为模拟染料废水,系统考察了活性炭(AC)对亚甲基蓝的吸附性能。计算得到了△G0、△H0、△S0等几个热力学参数。实验结果表明:活性炭的吸附性能取决于吸附时间、废水pH值和废水温度。吸附行为符合二级反应速率方程所描述的规律和Langmuir吸附等温式。废水pH值的升高有利于提高最终吸附处理的效果。活性炭对亚甲基蓝的吸附是一个自发的、弱吸热的物理过程,温度的升高有利于吸附的进行。

【Abstract】 The adsorption capacity of methylene blue in wastewater by activated carbon was measured,thus having systematically studied the Property about the intermissive adsorption of methylene blue.The thermodynamic parameters such as △G0、△H0 and △S0 have been calculated.The results show that the property of adsorption depends on adsorption time、pH and temperature.The adsorption of activated carbon for Methylene Blue fits well with the pseudo-second-rate equation and Langmuir isotherm model.The higher pH of dyestuff wastewater is,the better treatment effect can be obtained.Meanwhile,the adsorption of activated carbon for Methylene is a spontaneously and endothermically physical process,temperature increases being beneficial to adsorption.

【关键词】 吸附活性炭亚甲基蓝吸附时间pH温度
【Key words】 adsorptionactivated carbonmethylene blueadsorption timepHtemperature
  • 【文献出处】 能源环境保护 ,Energy Environmental Protection , 编辑部邮箱 ,2008年06期
  • 【分类号】X703.5
  • 【被引频次】7
  • 【下载频次】519
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