【摘要】 采用溶剂热合成方法,得到了2种Cr(Ⅲ)配合物:Cr(oxinate)3.CH3CH2OH(1)和Cr(oxinate)3.CH3OH(2).对2种化合物的单晶体进行X-射线衍射分析,确定了分子结构和晶体结构.2种化合物均为单斜晶系,P2(1)/n空间群.晶胞参数分别为:a=1.1255nm,b=1.3281nm,c=1.6783nm,α=90°,β=94.479°,γ=90°,V=2.5011nm3,Z=4,F=1.052,R=0.0511(1);a=1.0912nm,b=1.3136nm,c=1.6847nm,α=90°,β=97.73°,γ=90°,V=2.3930nm3,Z=4,F=1.098,R=0.0467(2).结构解析表明,2种化合物均存在着分子内氢键.对2种化合物的UV-VIS-NIR和荧光光谱进行了测定、分析指认和对比.更多还原

【Abstract】 Two complexes,Cr(oxinate)3·CH3CH2OH(1)and Cr(oxinate)3·CH3OH(2),have been hydrothermally synthesized.The structures of the two complexes were determined by single crystal X-ray diffraction.Two complexes all crystallize in monoclinic space group P2(1)/n with cell parameters of a=1.125 5 nm,b=1.328 1nm,c=1.678 3 nm,α= 90°,β=94.497°,γ=90°,V=2.501 1 nm3,Z=4,F=1.052,R=0.051 1(1);a=1.091 2 nm,b= 1.313 6 nm,c= 1.684 7 nm,α= 90°,β=97.73°,γ=90°,V=2.393 0 nm3,Z=4,F=1.098,R=0.046 7(2).Constructions confirm that in the molecules of the two complexes there exist hydrogen-bonds.In addition.The UV-VIS-NIR,and fluorescence spectra of the two complexes were measured,analyzed and compared.更多还原