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变色酸2R-β-环糊精体系共振光散射光谱法测定农药氰戊菊酯
Determination of Fenvalerate by Resonance Scattering Spectrometry Based on the Reaction with Chromotropic Acid 2R and β-Cyclodextrin
【摘要】 在pH 2.87的B-R缓冲溶液中,氰戊菊酯与变色酸2R反应,在423nm波长处产生稍有增强而稳定的共振散射信号,而β-环糊精的加入进一步明显敏化该共振光散射信号,且散射强度与氰戊菊酯的质量浓度在0.02~0.50mg·L-1范围内呈线性关系,其检出限(S/N=3)为0.016mg·L-1。该方法用于地面水、果品及蔬菜等样品中氰戊菊酯的测定,测得回收率在86.0%~113.0%之间,测得结果的相对标准偏差(n=5)在1.6%~6.0%之间。
【Abstract】 It was found that in a B-R buffer solution of pH 2.87,intensity of the resonance scattering at 423 nm due to the reaction between fenvalerate(FVR)and chromotropic acid 2R(CTA 2R)was enhanced significantly by the presence ofβ-cyclodextrin(β-CD),and that linear relationship between magnitude of intensity of the resonance scattering signal and concentration of FVR was obtained in the range of 0.02-0.50 mg·L-1,with detection limit of 0.016 mg·L-1.The proposed method has been applied to the determination of FVR in some samples of surface water,fruits and vegetable,giving values of recovery in the range of 86.0%—113.0%,and of RSD’s(n=)in the range 1.6%-6.0%.
【Key words】 Resonance scattering spectrometry; Fenvalerate; Chromotropic acid 2R; β-Cyclodextrin;
- 【文献出处】 理化检验(化学分册) ,Physical Testing and Chemical Analysis(Part B:Chemical Analysis) , 编辑部邮箱 ,2008年09期
- 【分类号】TS207.53
- 【被引频次】4
- 【下载频次】90