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Crystallization dynamics of supersaturated NaClO4 aerosols studied by high-speed photography

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【Author】 WANG Feng, ZHAO LiJun & ZHANG YunHong Institute of Chemical Physics, Beijing Institute of Technology, Beijing 100081, China

【摘要】 Single supersaturated NaClO4 aerosol droplets on a quartz substrate were observed by a high-speed video camera for their morphologic changes with decreasing relative humidity (RH). The supersatu- rated droplets were found to form anhydrous NaClO4 at ~10% RH. Three stages were roughly observed in this process, i.e., the main stem appearance, primary and secondary branches growth, and the deep dehydration. The main stem grew steadily and finished in 120 ms. Affected by both crystal precipitation and water evaporation, primary branches grew for 1200 ms, accompanied by a slower growth of sec- ondary branches. The deep dehydration was more complicated, and lasted for a longer time.

【Abstract】 Single supersaturated NaClO4 aerosol droplets on a quartz substrate were observed by a high-speed video camera for their morphologic changes with decreasing relative humidity (RH). The supersatu- rated droplets were found to form anhydrous NaClO4 at ~10% RH. Three stages were roughly observed in this process, i.e., the main stem appearance, primary and secondary branches growth, and the deep dehydration. The main stem grew steadily and finished in 120 ms. Affected by both crystal precipitation and water evaporation, primary branches grew for 1200 ms, accompanied by a slower growth of sec- ondary branches. The deep dehydration was more complicated, and lasted for a longer time.

【基金】 Supported by the National Natural Science Foundation of China (Grant Nos. 20473012, 20673010 & 20640420450);the “111” Project (Grant No. B07012);the China Postdoctoral Science Foundation (Grant No. 20070410466);the Incuba-tion and Reward Foundation for Excellent Doctoral Dissertation of Beijing Institute of Technology
  • 【文献出处】 Chinese Science Bulletin ,科学通报(英文版) , 编辑部邮箱 ,2008年14期
  • 【分类号】TB84
  • 【被引频次】2
  • 【下载频次】27
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