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聚硅硫酸铁的合成及其在油田污水处理中的应用

Synthesis of Polysilicon Ferric Sulfate and its Application in Oily Wastewater Treatment

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【作者】 俞日华; 赵晓非; 马春曦; 陈培涛; 谭小红; 才华;

【Author】 Yu Rihua~1 Zhao Xiaofei~2 Ma Chunxi~2 Chen Peitao~2 Tan Xiaohong~2 Cai Hua~2 (1.Petroleum Engineering College,Daqing Petroleum Institute,Daqing 163318; 2.Chemistry and Chemical Engineering College,Daqing Petroleum Institute,Daqing 163318)

【机构】 大庆石油学院石油工程学院; 大庆石油学院化学化工学院;

【摘要】 采用复合共聚生产工艺合成了聚硅硫酸铁。考察了pH、二氧化硅含量和温度对硅酸聚合时间的影响以及Fe/SiO2摩尔比对聚硅硫酸铁用于油田污水处理的除污效果的影响。确定优化合成条件为:pH 4~5,二氧化硅含量4%,温度20~30℃,Fe/SiO2摩尔比0.8。对透光率为26%的含油污水进行处理,最佳投药量为800 mg/L,处理后污水透光率可达98%。

【Abstract】 Polysilicon ferric sulfate(PFSS)was synthesized by copolymerization.The effects of pH,content of silica and temperature on silicate polymerization time were examined,and the effect of molar ratio of Fe to SiO2 on the decontamination of PFSS in oily wastewater treatment was studied.The optimal synthesis conditions were as follows:pH 4~5,the content of silica 4%,temperature 20~30℃,n(Fe):n(SiO2)=0.8.When the transmission rate of oily wastewater was 26%,the best dosage of PFSS was 800 mg/L,and the transmission rate of treated sewage was up to 98%.

【基金】 黑龙江省教育厅基金项目(项目批号:11513010)。
  • 【文献出处】 精细石油化工进展 ,Advances in Fine Petrochemicals , 编辑部邮箱 ,2008年05期
  • 【分类号】X741
  • 【被引频次】1
  • 【下载频次】145
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