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稀土La对AZ91D镁合金在Nacl溶液中耐蚀性的影响

EFFECT OF La ON THE CORROSION RESISTANCE OF AZ91D MAGNESIUM ALLOY IN NaCl AQUEOUS SOLUTION

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【作者】 吴国华樊昱翟春泉丁文江

【Author】 WU Guohua~(1,2)) FAN Yu~(1,3)) ZHAI Chunquan~(1)) DING Wenjiang~(1,2)) 1)National Engineering Research Center of Light Alloy Net Forming,Shanghai Jiao Tong University,Shanghai 200240 2)State Key Laboratory of Metal Matrix Composite,Shanghai Jiao Tong University,Shanghai 200240 3)Research Department of Wear-Resistant Materials Engineering Machinery,Guangzhou Research Institute of Nonferrous Metals,Guangzhou 510650

【机构】 上海交通大学轻合金精密成型国家工程研究中心

【摘要】 AZ91D合金中加入1%La(质量分数)后,不但形成了条状的Al11La3相和块状的Al8LaMn4相,而且在粗大β相(Mg17Al12)周围形成了许多细小的层片状β相,并使β相进一步网状化.这些细小的层片状β相明显阻碍了腐蚀的扩展,提高了AZ91D镁合金的耐蚀性.条状的Al11La3相和块状的Al8LaMn4相都属于阴极耐蚀相.其中Al11La3相由于较小的阴极面积,对加速其周围镁基体的腐蚀不起明显作用;而块状的Al8LaMn4相阴极面积较大,与基体构成微电偶腐蚀,加速了基体的腐蚀.

【Abstract】 The microstructure,corrosion morphology and corrosion product of AZ91D and AZ91D-1.0La alloys were investigated.With the addition of 1%La(mass fraction)in AZ91D,not only rod-like Al11La3 and blocky Al8LaMn4 phases,but also much fine laminarβphase(Mg17Al12) around bulkβphase formed.The fine laminarβphase obviously restrained the further development of corrosion,which greatly improved the corrosion resistance of AZ91D.Al11La3 phase is cathodic phase,but this phase did not accelerate corrosion ofα-Mg matrix because rod-like Al11La3 only offers a small cathodic area.However,blocky Al8LaMn4 phase obviously accelerated corrosion ofα-Mg matrix because of its large cathodic area.

【基金】 国家重点基础研究发展计划项目2007CB613701;“十一五”国家科技支撑计划重点项目2006BAE04B07-2;上海市优秀学科带头人计划项目08XD14020资助~~
  • 【文献出处】 金属学报 ,Acta Metallurgica Sinica , 编辑部邮箱 ,2008年10期
  • 【分类号】TG174.3
  • 【被引频次】49
  • 【下载频次】439
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