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Pd-Si binary bulk metallic glass

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【Author】 YAO KeFu & CHEN Na Key Laboratory of Advanced Materials Processing Technology,Department of Mechanical Engineering,Tsinghua University,Beijing 100084,China

【摘要】 Pd80+xSi20-x (x=0,1,and 2) binary metallic glasses with the diameter ranging from 7 to 8 mm were prepared by a combination of fluxing and water quenching or air cooling. Thermal analysis results show that with increasing Si content,the glass transition temperature Tg,the initial crystallization temperature Tx and the onset crystalliza-tion temperature Tp of Pd-Si binary glassy alloys increase. Moreover,the super-cooled liquid region reaches 61 K. It indicates that Pd-Si binary alloys possess large glass forming ability,which can be greatly improved by fluxing treatment.

【Abstract】 Pd80+xSi20-x (x=0,1,and 2) binary metallic glasses with the diameter ranging from 7 to 8 mm were prepared by a combination of fluxing and water quenching or air cooling. Thermal analysis results show that with increasing Si content,the glass transition temperature Tg,the initial crystallization temperature Tx and the onset crystalliza-tion temperature Tp of Pd-Si binary glassy alloys increase. Moreover,the super-cooled liquid region reaches 61 K. It indicates that Pd-Si binary alloys possess large glass forming ability,which can be greatly improved by fluxing treatment.

【基金】 the National Basic Research Program of China (Grant No. 2007CB613905);the National Natural Science Foundation of China (Grant Nos. 50671050 and 50431030)
  • 【文献出处】 Science in China(Series G:Physics,Mechanics & Astronomy) ,中国科学(G辑:物理学 力学 天文学)(英文版) , 编辑部邮箱 ,2008年04期
  • 【分类号】O482
  • 【被引频次】8
  • 【下载频次】39
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