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含酚羟基Schiff碱化合物的阴离子识别研究
Anion recognition of Shiff base bearing phenolic hydroxy groups
【Abstract】 Novel receptors based on Schiff base bearing phenolic hydroxy groups have been synthesized and characterized.The UV-vis date indicates that a 1∶1 stoichiometry complex is formed between receptors and F-.1H NMR titrations and solvation effect confirmed hydrogen interaction between the receptors and anion.The results indicate that the affinity is related to the number of hydrogen bond.Hence,the receptors 1,2 and 3 can act as fluoride ion sensors even in the presence of other hahide ions.
【基金】 国家自然科学基金(20371040)项目资助;教育部科学技术研究重点项目(205161)资助;甘肃省中青年科技基金(3YS051-A25-01)项目资助
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2008年07期
- 【分类号】O641.3
- 【被引频次】16
- 【下载频次】346