节点文献
α,β-不饱和酰基取代的酰亚胺衍生物合成方法的研究
Study on the synthetic method of α,β-unsaturated acyl-substituted imido derivatives
【Abstract】 α,β-unsaturated acyl-substituted imido derivatives are a kind of important electron-deficient alkenes and widely applied in synthesis.In this paper,a new synthetic method of these alkenes is developed and the catalytic mechanism is discussed.With LiCl as the catalyst,the products are synthesized with succinimides or phthalimide、crotonic anhydride in the present of triethylamine at low temperature.The reactions proceed smoothly in the given condition with good yields.
【关键词】 巴豆酸酐;
N-巴豆酰基琥珀酰亚胺;
N-巴豆酰基邻苯二甲酰亚胺;
合成;
【Key words】 crotonic anhydride; N-crotonoylsuccinimide; N-crotonoylphthalimide; synthesis;
【Key words】 crotonic anhydride; N-crotonoylsuccinimide; N-crotonoylphthalimide; synthesis;
【基金】 国家自然科学基金资助项目(20272011)
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2008年05期
- 【分类号】O623.6
- 【被引频次】2
- 【下载频次】132