【摘要】 优化了N,N’-二(2-吡啶基)-1,6,7,12-四(4-叔丁基苯氧基)-3,4:9,10-苝酰亚胺的合成方法,得到一种简单有效的在苝酰亚胺的酰胺和bay位置同时取代的方法.对其结构进行了表征,研究了其溶液态和薄膜态的光学性质和电化学性质.并且对其能级结构和电荷分布进行了分子模拟。更多还原

【Abstract】 The synthetic methods of N,N’-bi(2-pyridyl)-1,6,7,12-terta(4-tert-butylphenoxy)-perylene-3,4:9,10-tetracarboxylic diimide were optimized.A simple and effective synthetic method to substitute at both imide and bay positions was gained.The structure was investigated.And its optical and electrochemical properties were studied in both solution and thin films.And the theoretical calculations were also carried out regarding the energy levels and electron distribution.更多还原