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化学沉淀法用于多种形貌ZnS纳米晶的可控合成
Shape-controlled Synthesis of ZnS Nanocrystals by a Chemical Precipitation
【摘要】 以辛基酚聚氧乙烯醚(OP-10)为表面活性剂,二甲基甲酰胺(DMF)/水为溶剂,用沉淀法制备了纳米球、纳米棒、纳米片等多种形貌可控的ZnS纳米晶,并且用透射电子显微镜、X射线衍射、紫外吸收、荧光光谱对其进行了表征,并且分析了其形貌转变机理.
【Abstract】 A facile approach to synthesize ZnS nano particles,nanorods and nanosheets stabilized by OP-10 in the mixed solvents of dimethylformamide and water was reported.Different morphology of the nanoparticles could be realized by changing the quantity of OP-10 and the refluxing time.The as-synthesized ZnS nanocrystals were characterized by X-ray diffraction,transmission electron microscopy,photoluminescence and the UV-visible absorption spectra.The possible mechanism for the formation of morphology diversity was described.
【基金】 国家自然科学基金(Nos.50028302,50433030)资助项目
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2008年08期
- 【分类号】TB383.1
- 【被引频次】16
- 【下载频次】619