【摘要】 以高氯酸锌、1,2-丙二胺(1,2-pn)为原料在甲醇介质中反应,合成得到了新颖单核锌配合物[Zn(1,2-pn)3](ClO4)2,用元素分析、IR、1HNMR和热重分析等手段对该化合物的结构进行了表征,并用单晶X-射线衍射法测得其晶体结构为单斜晶系,空间点群为C2/c,晶体学参数为:a=2.971 4(11)nm,b=0.978 0(4)nm,c=1.780 3(5)nm,α=90.00°,β=122.90(2)°,γ=90.00°,V=4.344(3)nm3,Dc=1.488 g/cm3,Z=8,F(000)=2 032,μ=1.421 mm-1。更多还原

【Abstract】 A novel mononuclear complex [Zn(1,2-pn)3](ClO4)2 was synthesized based on the reaction of zinc perchlorate hexahydrate with propane-1,2-diamine in methanol medium.Its structure was characterized by elemental analysis,IR spectrometry,1HNMR and thermal analysis.The crystal structure of the title compound was also determined by X-ray single crystal diffractometry.The crystal belonged to a monoclinic system with space group C2/c,and crystallographic data of the compound were:a=2.971 4(11) nm,b=0.978 0(4) nm,c=1.780 3(5) nm,α=90.00°,β=122.90(2) °,γ=90.00°,V=4.344(3) nm3,Dc=1.488 g/cm3,Z=8,F(000)=2 032,and μ=1.421 mm-1.更多还原