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PBO/MSA体系的溶液性质研究

Study on the Solution Properties of PBO/MSA

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【作者】 林珩承建军刘子涛庄启昕韩哲文

【Author】 LIN Heng,CHENG Jian-jun,LIU Zi-tao,ZHUANG Qi-xin,HAN Zhe-wen(East China University of Science and Technology,Shanghai 200237,China)

【机构】 华东理工大学

【摘要】 运用Ubbelohde式粘度计测定PBO/MSA溶液的粘度,采用稀释外推法对溶液浓度和粘度的关系进行了分析,结果发现当溶液浓度不太低时,PBO高分子链在溶液中存在聚集现象;当溶液浓度极低时,PBO/MSA溶液粘度随着浓度的降低而急剧增大,呈现"聚电解质效应";同时研究了PBO的重均分子量与特性粘数的关系,结果显示用半刚性聚电解质链模型来关联两者关系比刚性棒状模型更合适。

【Abstract】 The property of PBO/MSA solution was studied by using Ubbelohde viscometer.The effect of the solution consentration on the viscosity was analyzed by diluted extrapolation method.The results showed that the PBO chain conglomerate in the solution with low concentration.And there is a "polyelectrolyte effect" in PBO/MSA solution with an infinite diluted concentration.The effect of the [η] of PBO on its molecular weight was also investigated.The results revealed that the third-order polynomial based on the semi-rigid polyelectrolyte model is better than the Mark-Houwink equation in terms of the rigid rod-like model in relating the [η] and Mw of PBO.

【关键词】 PBO溶液性质特性粘数分子量
【Key words】 PBOsolution propertyintrinsic viscositymolecular weight
【基金】 国家科技部863计划(2002AA305109);上海市重点学科建设资助项目
  • 【文献出处】 航空材料学报 ,Journal of Aeronautical Materials , 编辑部邮箱 ,2008年05期
  • 【分类号】TQ340.1
  • 【被引频次】1
  • 【下载频次】103
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