【摘要】 本文主要研究了邻苯二甲酸二丁酯(DBP)在氧化体系(乙腈/水)、还原体系(甲醇/水、特丁醇/水)、纯水三种体系下的电子束辐射降解效应。用HPLC测定了四种溶液下DBP在电子束辐射前后的浓度,GC/MS对乙腈/水、甲醇/水、和纯水溶液的辐射降解产物进行了分析。结果表明:DBP辐射降解遵循一级动力学方程。在辐照剂量仅仅为0.5kGy时,DBP浓度为7.8mg/L时,除特丁醇/水溶液外,DBP降解率已经达到85%以上。三种溶液下的降解产物都有邻苯二甲酸二乙酯、邻苯二甲酸单丁酯、邻苯二甲酸二异丁酯。最后对DBP的电子束辐射降解机理作了初步探讨。更多还原

【Abstract】 E-beam degradation of dibutyl phthalate (DBP) in oxidation system (acetonitrile/water), reduction system (methanol/water, t-BuOH/water), and pure water systems was investigated. DBP concentration in the four solutions was determined by HPLC, and the degradation products were analyzed by GC/MS. The results showed that the DBP degradation followed pseudo-first-order kinetics. DBP in a concentration of 7.8mg/L, in all solutions but the t-BuOH/water, could be degraded in a rate of over 85% by 0.5 kGy E-beam irradiation The degradation products included diethyl phthalate, bis(2-methylpropyl)ester, and 1,2-Benzenedicarboxylc acid in the three solutions. Finally, mechanism of the DBP degradation was discussed.更多还原