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代森锰锌及其代谢物乙撑硫脲在马铃薯和土壤中的残留动态

RESIDUE DYNAMICS OF MANCOZEB AND ITS METABOLITE ETHYLENETHIOUREA IN POTATO AND SOIL

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【作者】 秦冬梅徐应明黄永春孙扬何丽丽

【Author】 QIN Dong-mei1 XU Ying-ming2 HUANG Yong-chun2 SUN Yang2 HE Li-li3(1 Institute for the Control of Agrochemicals,Ministry of Agriculture,Beijing,100026, China;2 Department of Pollution Control,Agro-Environmental Protection Institute, Ministry of Agriculture,Tianjin,300191, China;3 School of Biology and Chemical, Tianjin University of Technology, Tianjin,300191, China)

【机构】 农业部农药检定所残留室农业部环境保护科研监测所天津理工大学生化学院 北京100026污染防治研究室天津300191

【摘要】 采用田间试验方法研究代森锰锌及其代谢物乙撑硫脲(ETU)在马铃薯和土壤中的残留动态.气相色谱法定量分析,本方法马铃薯中代森锰锌和ETU的平均回收率分别为85.41%—95.47%和87.71%—92.19%;土壤中代森锰锌和ETU的平均回收率分别为85.61%—103.09%和91.08%—94.46%.结果表明:代森锰锌和ETU在马铃薯茎叶中消解较快,在合肥市和天津市两地其消解半衰期分别为6.41—7.89d和6.16—7.15d;在土壤中的消解半衰期分别为5.26—7.71d和9.80—10.16d.在马铃薯上使用了72%锰锌.霜脲可湿性粉剂,按照推荐剂量的2倍(3240gaig·ha-1)最多施药4次,采收期距最后一次施药7d,马铃薯中代森锰锌残留量小于1.0mgg·kg-1,ETU小于0.05mg·kg-1.说明该药为低残留、易消解农药.

【Abstract】 A field experiment was conducted to reveal dynamics of Mancozeb and its metabolite ethylenethiourea(ETU) residues in potato and soil. The results showed that the average recoveries were 85.41%—95.47% for Mancozeb and 87.71%—92.19% for ETU in potato, and 85.61%—103.09% for Mancozeb and 91.08%—94.46% for ETU in soil, respectively. Mancozeb and ETU dissipated rapidly in potato. The half-life of the former(Hefei city)in potato was 6.41d—7.89d and of the latter(Tianjin city)6.16d—7.15d. And they also degraded rapidly in the soil, with their half-life being 5.26d—7.71d and 9.80d—10.16d, respectively. The results of the two-year experiments showed when the potato was sprayed four times with 3240gai·ha-1 Mancozeb/cymoxanil 72% WP,and the last application was done 7 days before harvesting,the residue of Mancozeb in potato was lower than 1.0 mg·kg-1 and ETU residue below 0.05 mg·kg-1,demonstrating that it is safe to apply Maneozeb to potato with the recommended rate.

【关键词】 代森锰锌乙撑硫脲马铃薯土壤残留
【Key words】 Mancozebethylenethioureapotatosoilresidue
【基金】 农业部农药登记残留试验项目
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,2008年03期
  • 【分类号】S481.8
  • 【被引频次】43
  • 【下载频次】748
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