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介孔/大孔TiO2-SiO2复合氧化物材料的制备与表征

Preparation and characterization of meso/macro-porous composite oxide TiO2-SiO2

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【作者】 吴俊升李晓刚董超芳张新

【Author】 Wu Junsheng Li Xiaogang Dong Chaofang Zhang Xin(School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083)

【机构】 北京科技大学材料科学与工程学院北京科技大学材料科学与工程学院 北京100083北京100083

【摘要】 采用正硅酸甲酯和钛酸丁酯作为硅和钛的前驱体,在溶胶-凝胶过程中添加非离子表面活性剂C16EO10作为结构导向剂合成双孔结构硅钛复合氧化物材料。扫描电镜(SEM)以及N2吸附/脱附法分析表明,材料具有三维连续大孔和骨架介孔的双孔分布结构。通过骨架元素分析(EDS)和X射线衍射分析可知,制备过程中添加的钛可以全部进入凝胶骨架中,且钛在骨架中的分散性较好。采用Hammett指示剂法和吡啶吸附红外光谱法分析了材料表面固体酸性,结果显示,硅钛复合氧化物属于中强酸,酸强度H0在-5.6~-3.0之间的酸中心数大约为0.30 mmol/g左右。硅钛材料表面含有较丰富的L酸位和相对较少的B酸位。

【Abstract】 Bimodal porous titania-silica composite oxide were prepared via sol-gel method with an addition of nonionic surfactant C16EO10 as the structure-directing agent.Tetramethoxysilane and titanium tetrabutoxide were used as the silicon and titanium precursors,respectively.Scanning electron microscopy and N2 adsorption/desorption measurements indicated that the composite oxide in possession of interconnected macropores and texture mesopores.By means of energy dispersive spectroscopy and X-ray diffraction,it was proved that the initially added titanium could be totally incorporated in the gel network and highly dispersed.The acidity characters of titania-silica were studied by Hammett indicator method and infrared spectroscopy.Experimental results showed that titania-silica composite oxide synthesized by sol-gel method were mild strong solid acids,contained abundant Lewis acid sites and relatively poor Brnsted acid sites,and the mount of acid with acid strength H0 of-5.6~-3.0 was 0.30 mmol/g.

【基金】 国家高技术研究发展计划(“863”计划)(项目编号2006AA05Z306);北京市教育委员会共建项目建设计划资助(项目编号:SYS100080419)
  • 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2008年05期
  • 【分类号】O643.36
  • 【被引频次】11
  • 【下载频次】515
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