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腐殖酸钠抑制氧化铝熟料溶出二次反应机理初探

Mechanism for humic acid sodium to inhibit secondary reaction in clinker extraction process

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【作者】 张程忠于海燕张立强刘欣毕诗文

【Author】 ZHANG Chengzhong1,2,YU Haiyan1,ZHANG Liqiang3,LIU Xin1,BI Shiwen1(1School of Materials and Metallurgy,Northeastern University,Shenyang 110004,Liaoning,China;2Aluminum Corporation of China Limited,Beijing 100814,China;3Shanxi Branch Company,Aluminum Corporation of China Limited,Hejin 043300,Shanxi,China)

【机构】 东北大学材料与冶金学院中国铝业股份有限公司山西分公司东北大学材料与冶金学院 辽宁沈阳110004 中国铝业股份有限公司北京100814辽宁沈阳110004山西河津043300

【Abstract】 Humic acid sodium was used as an inhibitor to the secondary reaction in the process of clinker extraction.When the addition of humic acid sodium to clinker was up to about 0.43%,the extraction efficiency of alumina and caustic from clinker will be increased by 3.87% and 4.51%,respectively.Its inhibition mechanism was studied by the determination of infrared(NIR)spectra and the concentrations of SiO2 and Ca2+ in the extracted solution.The results showed that the big molecules of humic acid sodium enwrapped dicalcium silicate surface,which prevented dicalcium silicate from contacting with the solution.At the same time,the anions dissociating from humic acid sodium could combine with Ca2+,which resulted in the concentration reduction of Ca2+ in the solution.Therefore,it was inhibited to form hydrated aluminosilicate silicate which caused the loss of sodium aluminate.

【基金】 国家自然科学基金项目(50674028);中国铝业股份公司资助~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2008年02期
  • 【分类号】TF821
  • 【被引频次】18
  • 【下载频次】189
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