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微乳液法腈纶接枝聚苯胺及其性能研究

Synthesis of acrylic fiber with grafting polyaniline by microemulsion method and its properties

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【作者】 王新波王祥荣王建军

【Author】 Wang XinBo~1 Wang XiangRong~2 Wang JianJun~1 (1.Science Division of Materials and Chemistry & Chemical Engineering,Soochow University,Suzhou Jiangsu 215123,China) (2.College of Textile & Clothes,Soochow University,Suzhou Jiangsu 215021,China)

【机构】 苏州大学材料与化学化工学部苏州大学纺织与服装学院

【摘要】 采用低温等离子体技术对腈纶纤维表面进行处理,使用苯胺微乳液在腈纶表面进行接枝聚合,对腈纶进行改性处理,通过增重率、导电率测试、接枝聚合的因素和接枝聚合对腈纶纤维结构、导电性能和强力进行分析评价;扫描电镜和红外测试显示聚苯胺成功接枝上腈纶表面;腈纶接枝聚苯胺后,导电性能增加,强力变化不大,但伸长率略有降低。

【Abstract】 The surface of acrylic fiber was treated by non-thermal plasma technology,so that aniline in microemul- sion was polymerized and grafted on the surface of the fiber.The modified fibers were checked by weight-gain ratio,con- ductivity and grafting polymerization conditions.The structure,electric properties and mechanism of modified fibers were assessed,the results show SEM and FTIR showed that polyaniline was grafted onto the acrylic fiber surface successly;af- ter grafting polyaniline,the electric property of acrylic fiber were improved,tension stregth had little change and the break elongation decreased slight.

  • 【文献出处】 合成技术及应用 ,Synthetic Technology & Application , 编辑部邮箱 ,2008年03期
  • 【分类号】TQ342.31
  • 【被引频次】3
  • 【下载频次】162
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