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含茂基咔唑镧系金属有机配合物的合成
Synthesis of Organolanthanide Complexes Containing Cyclopentadienyl and Carbazole
【摘要】 以咔唑和正丁基锂为原料,采用Schlenk技术合成了一系列新的含茂基咔唑镧系金属有机配合物——Cp2LnL(Cp=环戊二烯基;Ln=Yb,Er,Ho,Tb,Gd,Sm;L=咔唑基),其结构经IR,MS和元素分析表征。
【Abstract】 A series of new organolanthanide complexes containing cyclopentadiene and carbazole complex,Cp2LnL(Cp=cyclopentadienyl;Ln=Yb,Er,Ho,Tb,Gd,Sm;L=carbazole),were synthesized by Schlenk manipulative technique from butyl lithium and carbazole.The structures were characterized by IR,MS and elemental analysis.
【关键词】 咔唑;
镧系金属有机配合物;
环戊二烯;
合成;
【Key words】 carbazole; organolanthanide complex; cyclopentadiene; synthesis;
【Key words】 carbazole; organolanthanide complex; cyclopentadiene; synthesis;
- 【文献出处】 合成化学 ,Chinese Journal of Synthetic Chemistry , 编辑部邮箱 ,2008年02期
- 【分类号】O641.4
- 【下载频次】219