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稀土钒酸钇体系薄膜的制备和发光性质研究

Preparation and Properties of RE YVO4 System Film

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【作者】 曹铁平李跃军于敏

【Author】 CAO Tie-ping1,LI Yue-jun1,YU Min2(1.Department of Chemistry,Baicheng Normal College,Jilin Baicheng 137000,China;2.Department of Chemistry,Northeast Normal University,Jilin Changchun 130024,China)

【机构】 白城师范学院化学系东北师范大学化学学院

【摘要】 以无机钒酸钇(YVO4)为主要原料制备了稀土离子Eu3+掺杂的纳米发光薄膜,研究了薄膜的形态结构和发光性能.薄膜的发射强度和寿命随着x(Eu3+)的增加而增大,在x(Eu3+)为7%时强度达到最大,随后随着x(Eu3+)的增加而减小;随着烧结温度从500℃提高到700℃,薄膜发光强度增强,寿命逐渐加长.

【Abstract】 Nano-luminescent film(YVO4/Eu) doped with Eu3+ions has been prepared with inorganic YVO4 as its main raw materials.The structure and fluorescence properties of the film have been studied.The result indicates that the film fluorescence lifetime increases along with the augment of the doping Eu3+ concentration.When it reaches the best luminous density to 7 %,the intensity attains to its maximum and the life-span value is the longest,afterwards the life of film reduces with the increase of concentration.Along with agglomeration temperature enhancement from 500 ℃ to 700 ℃,the film luminous intensity elevates,the life lengthens gradually.

【关键词】 稀土金属钒酸钇纳米发光薄膜
【Key words】 rare earth ionsYVO4nano-luminousthin film
【基金】 国家自然科学基金(50225205,20271048)
  • 【文献出处】 河北师范大学学报(自然科学版) ,Journal of Hebei Normal University(Natural Science Edition) , 编辑部邮箱 ,2008年06期
  • 【分类号】O614.3
  • 【下载频次】208
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