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采用双外推法计算稻壳热解活化能
Calculation of the Activation Energy for Thermolysis of Rice Husks Using Double Exploration Method
【摘要】 采用双外推法确定了稻壳热解的最概然机理函数为Avrami-Erofeev方程G(α)=[-ln(1-α)]4,热解活化能约为70 kJ.mol-1,小于文献报道的松木等木质纤维素类生物质的热解活化能(一般大于100 kJ.mol-1),这可能与稻壳灰分较高,起到催化热解作用有关。
【Abstract】 The most probable mechanism function for describing thermolysis of rice husks has been detected to be Avrami-Erofeev equation {G(α)=[-ln(1-α)]4} and the activation energy for thermolysis is about 70 kJ·mol-1,which is less than those for thermolysis of lignocellulose such as pine wood provided by some literature(generally greater than 100 kJ·mol-1).The difference might be resulted from the catalytic effects played by the more abundant ash in the rice husks.
【关键词】 稻壳;
热解;
活化能;
双外推法;
【Key words】 rice husk; thermolysis; activation energy; double exploration method;
【Key words】 rice husk; thermolysis; activation energy; double exploration method;
【基金】 国家自然科学基金项目(20676002);国家重点基础研究项目(2007CB210206、2004CCA07300);安徽省高校青年教师科研“资助计划”项目(2006jp1075)
- 【文献出处】 化学与生物工程 ,Chemistry & Bioengineering , 编辑部邮箱 ,2008年07期
- 【分类号】O643.1
- 【被引频次】9
- 【下载频次】247