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La0.7Ce0.3(Fe1-xCox)11.44Si1.56(x=0.04、0.06、0.08)合金的结构与磁热效应

Structure and magnetocaloric effect of La0.7Ce0.3(Fe1-xCox)11.44Si1.56(x=0.04、0.06、0.08) alloys

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【作者】 刘涛陈云贵唐永柏肖素芬张恩耀王金伟

【Author】 LIU Tao,CHEN Yun-gui,TANG Yong-bai,XIAO Su-fen,ZHANG En-yao,WANG Jin-wei(School of Materials Science and Engineering,Sichuan University,Chengdu 610065,China)

【机构】 四川大学材料科学与工程学院

【摘要】 通过X射线衍射仪研究了1300℃退火1h后的La0.7Ce0.3(Fe1-xCox)11.44Si1.56(x=0.04、0.06、0.08)合金的相结构。采用振动样品磁强计研究了合金的磁性能。结果表明,合金主相具有NaZn13型结构,含有少量-αFe和LaFeSi杂相;x=0.04、0.06和0.08时,合金的居里温度Tc分别为230.8、261、288.9K,在1.1T的外磁场变化下,等温磁熵变|ΔSM|分别为2.44、1.86和1.55J/(kg.K)。

【Abstract】 The structures of La0.7Ce0.3(Fe1-xCox)11.44Si1.56 alloys which were annealed at 1300℃ for an hour were investigated by X-ray diffraction(XRD).The magnetic properties of alloys were investigated by vibrating sample magnetometer(VSM).The results showed that the major phase was of NaZn13-tye structure with a small amount of impurities composed of α-Fe and LaFeSi.The Curie temperatures Tc of alloys were 230.8,261,288.9K for x=0.04,0.06,0.08,respectively.Under the change of 1.1T the maximum values of isothermal magnetic entropy were 2.44,1.86 and 1.55J/(kg·K) for x=0.04,0.06,0.08,respectively.

【基金】 国家自然科学基金重点资助项目(50731007);国家高技术研究发展计划(863计划)资助项目(2007AA03Z440)
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,2008年09期
  • 【分类号】O482.6
  • 【被引频次】2
  • 【下载频次】162
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