【摘要】 以4,4′-二氨基二苯醚的-βCD包合物和甲苯-2,4-二异氰酸酯为单体,N,N-二甲基乙酰胺为溶剂,在室温合成了聚脲-βCD准轮烷(3a)。采用红外光谱(FT-IR)、热失重(TG)、核磁共振(1H-NMR)和X射线粉末衍射等手段分别对包合物和准轮烷(3a)进行了表征。结果表明,准轮烷(3a)链上-βCD的含量为42.9%(质量分数),热稳定性良好,是一类新颖的准轮烷。更多还原

【Abstract】 Inclusion complex compound of 4,4-oxydianiline was reacted with toluene-2,4diisocyanate in N,N-dimethylacetamide at room temperature to form a polyurea pseudorotaxanes(3a).The Inclusion complex and the polymer(3a) were characterized by FT-IR、TGA、1H-NMR and XRD. The results indicate that the polymer(3a) is a novel pseudorotaxane with good thermal stability and about 42.9% of β-CD on its chain.更多还原