【摘要】 在无任何掺杂酸的条件下,以过硫酸铵(APS)既为氧化剂、又为掺杂剂,采用无模板(template-free)自组装的方法制备了导电聚间甲基苯胺(PMT)空心微球.该空心微球的平均直径约为2μm,壳的厚度约为140nm.研究表明PMT空心微球是以球状的间甲苯胺胶束为软模板(soft-template)经过自组装过程而形成的.借助FTIR、UV-Vis和XRD等结构表征证实自组装的空心微球为导电态的聚间甲基苯胺.更多还原

【Abstract】 Self-assembled hollow microspheres of conductive poly（m-toluidine） （PMT） were simply synthesized by a template-free method in the presence of ammonium peroxydisulfate （APS） without adding an acidic dopant.The average diameter and the average shell thickness of the PMT hollow microspheres were measured to be 2 μm and 140 nm,respectively.Although without adding acids as the dopants,it has been demonstrated that the PMT hollow microspheres are identical to the conducting state of PMT due to proton （H₂SO₄） produced during the polymerization,which are conformed by FTIR,UV-Visible spectroscopy and room-temperature conductivity measured by the four-probe method,especially the pH value in reaction solution decreases with increasing the polymerization time.It was proposed that a spherical micelles composed of m-toluidine in aqueous solutions is served as a soft-template in forming the PMT hollow spheres via a self-assembly process.更多还原