节点文献
用氧化偶联聚合法合成新型电活性聚酰胺及其结构表征
Synthesis and Structure Characterization of a Novel Electroactive Polyamide via Oxidative Coupling Polymerization
【Abstract】 By oxidative coupling polymerization a novel electroactive polyamide,with fixed conjugated length of oligoaniline(amine-capped aniline pentamer)in the main chain,was successfully synthesized.The structure of the electroactive polyamide was confirmed via FTIR and NMR.The UV-Vis spectra were used to monitor the chemical oxidation process of the reduced polyamide.Moreove,its electrochemical behavior was investigated by cyclic voltammetry(CV)measurement.It was found that the obtained electroactive polyamide with amine-capped aniline pentamer segments had a quasi-reversible electrochemical property in the cyclic voltammetry,which was the same as polyaniline.Its electrical conductivity is about 1.24×10-6 S/cm at room temperature upon preliminarily protonic-doped experiment.
【Key words】 Electroactive polyamide; Oxidative coupling polymerization; Conducting polymer;
- 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2008年02期
- 【分类号】O633.22
- 【被引频次】1
- 【下载频次】168