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用氧化偶联聚合法合成新型电活性聚酰胺及其结构表征

Synthesis and Structure Characterization of a Novel Electroactive Polyamide via Oxidative Coupling Polymerization

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【作者】 崔丽莉晁单明茆卉张万金

【Author】 CUI Li-Li,CHAO Dan-Ming,MAO Hui,ZHANG Wan-Jin(Alan G.MacDiarmid Institute,Jilin University,Changchun 130012,China)

【机构】 吉林大学麦克德尔米德实验室吉林大学麦克德尔米德实验室 长春130012长春130012

【Abstract】 By oxidative coupling polymerization a novel electroactive polyamide,with fixed conjugated length of oligoaniline(amine-capped aniline pentamer)in the main chain,was successfully synthesized.The structure of the electroactive polyamide was confirmed via FTIR and NMR.The UV-Vis spectra were used to monitor the chemical oxidation process of the reduced polyamide.Moreove,its electrochemical behavior was investigated by cyclic voltammetry(CV)measurement.It was found that the obtained electroactive polyamide with amine-capped aniline pentamer segments had a quasi-reversible electrochemical property in the cyclic voltammetry,which was the same as polyaniline.Its electrical conductivity is about 1.24×10-6 S/cm at room temperature upon preliminarily protonic-doped experiment.

【基金】 国家“九七三”计划(批准号:G2003CB615604);国家自然科学基金(批准号:50473007,20674027)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2008年02期
  • 【分类号】O633.22
  • 【被引频次】1
  • 【下载频次】168
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