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游离和固定化SRB污泥处理含锌废水比较研究

Comparative Study on Treating Wastewater Containing Zinc by Free and Immobilized Sludge of SRB

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【作者】 王娜闵小波王云燕柴立元周敏

【Author】 WANG Na,MIN Xiao-bo,WANG Yun-yan,CHAI Li-yuan,ZHOU Min(School of Metallurgical Science and Engineering,Central South University,Changsha 410083,China)

【机构】 中南大学冶金科学与工程学院

【摘要】 采用聚乙烯醇(PVA)-硫酸铵包埋法对硫酸盐还原菌(SRB)进行固定化处理。以含锌废水为处理对象,利用内聚营养源固定化小球与游离污泥做对比实验,考察硫酸根去除率、锌离子去除率、出水COD值等因素,并借助EDX分析小球内部锌离子含量。实验结果表明,采用内聚营养源固定化小球,硫酸根去除率为55.7%,锌离子去除率达98%,出水COD<100mg/L,进行多次循环实验,出水锌离子浓度仍达到污水综合排放二级标准;采用游离污泥,硫酸根去除率为46.1%,锌离子去除率为98.2%,出水COD1800mg/L以上,用于二次处理废水,锌离子去除率仅为60.4%。固定化小球循环处理废水四次后,每克固定化小球内部锌离子含量为0.04364mg。

【Abstract】 Sulfate-reducing bacteria(SRB)were immobilized with PVA-(NH4)2SO4 method.Wastewater containing zinc was treated with immobilized beads with inner cohesive carbon source in contrast with free sludge to investigate removal efficiency of SO42-and Zn(II)as well as effluent COD,and content of Zn(II)within bead was analyzed by EDX.Results showed that removal efficiency of SO42-and Zn(II)with immobilized beads with inner cohesive carbon source was 55.7% and 98% respectively and effluent COD was less than 100mg/L.In repeated cyclic tests,Zn(II)concentration of treated water still satisfy Class II of discharge standard of wastewater.Removal efficiency of SO42-and Zn(II)with free sludge was 46.1% and 98.2% respectively,and COD was more than 1800mg/L.Removal efficiency of Zn(II)was only 60.4% in the second time test.Inner content of Zn(II)was 0.04364mg/g beads after fourth cycle of wastewater treatment.

【基金】 国家自然科学基金(50508044);湖南省科技计划攻关重大专项(05SK1003-1)
  • 【文献出处】 环境科学与技术 ,Environmental Science & Technology , 编辑部邮箱 ,2008年11期
  • 【分类号】X703.1
  • 【被引频次】13
  • 【下载频次】269
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