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酸性催化剂对刨花板苯酚液化残渣率的影响

Effects of Acid Catalysts on Liquefaction Residue Ratio of Particleboard in Phenol

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【作者】 朱本城赵广杰

【Author】 ZHU Ben-cheng,ZHAO Guang-jie(College of Material Science and Technology,Beijing Forestry University,Beijing 100083,China)

【机构】 北京林业大学材料科学与技术学院北京林业大学材料科学与技术学院 北京100083北京100083

【摘要】 为探讨酸性催化剂对刨花板-苯酚液化的影响,采用硼酸晶体、浓盐酸(37%)、磷酸(85%)和浓硫酸(98%)4种无机酸在不同温度条件下对刨花板(回收废弃刨花板和实验室自制刨花板)进行液化实验。结果表明:浓硫酸(98%)作为催化剂,对刨花板苯酚液化效果较好。在温度150℃、液化时间1.5h、液体比(苯酚/刨花板)为4、催化剂含量为6%的条件下,采用浓硫酸作为催化剂,可使回收废弃刨花板和实验室自制刨花板液化后的残渣率分别降至12.29%和9.95%。

【Abstract】 In order to study the effects of acid catalysts on particleboard liquefaction in pheno1,inorganic acids,such as boric acid,hydrochloric acid(37%) ,phosphoric acid(85%) and sulfuric acid(98%) ,were investigated at different temperature conditions.The residue ratio of particleboard liquefaction in phenol was applied as an indicator to find the optimum catalyst that has better effect on liquefaction. Results showed that sulfuric acid as a catalyst is better than that of other three acids.The ideal liquefaction yield can be obtained in the presence of sulfuric acid at such condition:liquefaction temperature 150℃,reaction time 1.5 h,liquid ratio(phenol/particleboard) 4,and the content of catalyst 6%. The residue ratio of recycled waste particleboard and the particleboard made in laboratory were 12.29% and 9.95% respectively.

【关键词】 刨花板苯酚液化催化剂残渣率
【Key words】 particleboardliquefactionacid catalystresidue ratio
【基金】 国家科技支撑计划课题:木质材料环境友好制造技术(2006BAD18B09)
  • 【文献出处】 中国人造板 ,China Wood-Based Panels , 编辑部邮箱 ,2008年05期
  • 【分类号】TS653
  • 【被引频次】4
  • 【下载频次】126
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