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单质硅在水基凝胶注模体系中稳定性的研究
Stabilization of High Solids Loading Slurry of Rough Silicon Particles for Gel Casting
【摘要】 在单质硅凝胶注模体系中,以PAA-NH4为分散剂,考察其对于高固相含量,稳定的单质硅料浆的影响。研究分散剂PAA-NH4在制备高固相含量,低粘度,高稳定性粗颗粒料浆中的作用。结果表明,当分散剂PAA-NH4用量为0.020-0.030 g/mL时,可以制备固相含量高达50%(体积分数),粘度较低,Zeta电位较高的料浆,适宜凝胶注模的操作。通过绘制等温吸附曲线,研究分散剂在颗粒表面的吸附形态,探讨该料浆稳定性的成因。
【Abstract】 The effect of poly(acrylic acid) ammonium(PAA-NH4) dispersant on high solids loading and stable silicon suspensions was characterized.The slurry of 50 vol%solids loading with low viscosity and high zeta potential was obtained using the concentration of PAA-NH4 of 0.020-0.030 g/mL in the premix solution.Absorption curve was measured and the absorption modality of PAA-NH4 on silicon particles was discussed.
- 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2008年S1期
- 【分类号】TQ174.6
- 【下载频次】69