【摘要】 综述了近来出现的一类有前途的多孔材料——金属-有机络合聚合物(MOCPs)吸附功能的设计策略与合成途径。通过配体结构的选择或修饰可赋予MOCPs特定吸附性的孔环境;或采用适当的设计和合成策略使过渡金属离子和有机配体形成的骨架结构对特定吸附质分子具有特定的选择性。为新型的多孔吸附剂的设计与制备提供了一种新思路。更多还原

【Abstract】 In the paper the approaches to design and synthesis of a new class of promising porous absorbents- metal-organic coordination polymers(MOCPs)are reviewed.It is possible to obtain porous mieroenvironment with spe- cific inner surfaces by selecting proper ligands or by ligands modified with specific functional groups and to prepare the MOCPs with a selectivity to some kind of target molecules by taking suitable strategies of design and synthesis.All of these provide us with a fire-new clue to new type porous sorbent design.更多还原