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晶化温度对铁铝复合吸附剂除磷效能影响

Effect of Crystallization Temperature on Phosphorus Removal of Iron-aluminum Composited Adsorbent

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【作者】 杨艳玲范茜李星李圭白

【Author】 YANG Yan-ling~1 FAN Qian~1 LI Xing~1 LI Gui-bai~2 1.Beijing Key Laboratory of Water Quality Science and Water Environment Recovery Engineering,Beijing University of Technology,Beijing 100022,China; 2.School of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China

【机构】 北京工业大学 北京市水质科学与水恢复工程重点实验室哈尔滨工业大学 市政环境工程学院 北京 100022北京 100022哈尔滨 150090

【摘要】 考察了不同晶化温度下制备的铁铝复合吸附剂去除PO43--P的性能以及pH值和共存干扰离子CO32-对其吸附去除PO43--P性能的影响.结果表明,晶化温度对铁铝复合吸附剂去除PO43--P的性能有显著影响,较低晶化温度下制备的铁铝复合吸附剂去除PO43--P效果明显优于高温制备的吸附剂;晶化温度的升高使晶体本身结构发生变化,导致比表面积降低,是其吸附性能下降的主要原因;较低晶化温度下制备的铁铝复合吸附剂去除PO43-P的性能受pH值影响较小,对水质适应性强;共存离子CO32--对铁铝复合吸附剂去除PO43-P的性能具有强抑制作用,应用中应该尽量避免这种负面干扰作用的存在.

【Abstract】 Performance of phosphate removal by iron-aluminum composited adsorbent is studied under different crystallization temperature.Influences of pH value and coexisting ions of CO32- to performance of adsorption phosphate removal are investigated.Results show that phosphorus removal performance of the adsorbent is influenced remarkably by crystallization temperature.Phosphorus removal performance of the adsorbent prepared at lower temperature has better performance than that at higher temperature.The main reason of decreasing adsorption performance is that the specific surface area is reduced by crystal structure change caused by increasing crystallization temperature.Phosphorus removal performance of the adsorbent prepared at lower temperature is less influence by pH value.The adsorbent shows good adaptability to water quality.Phosphorus removal performance of the adsorbent is played strongly inhibitory action by coexistent ion CO32-.The opposite negative interference action should be avoided in practical applications.

【基金】 国家自然科学基金(50378004);中国博士后科学基金(2005038040);北京市属市管高校人才强教计划资助项目(05004014200701);北京市自然基金(8082009).
  • 【文献出处】 北京工业大学学报 ,Journal of Beijing University of Technology , 编辑部邮箱 ,2008年05期
  • 【分类号】X703
  • 【被引频次】6
  • 【下载频次】153
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